LOL, I have some that will stand for it, and some, that have also been sprayed for a zillion years, that still wont. For those, I usually put on a halter and just hold the lead- and if they want to panic and go in a circle, they can go around me in a small circle while I keep spraying. I will talk to them in a quiet voice also and keep things quiet. They settle down quickly... the aged ones usually stand there, once the halter is on and they know they can't get away, LOL They may not like it, but they stand for it.
I never spray their face area. I put it on my hand and rub their face, being careful to avoid their eyes. Then dont forget to wash your hands!
I have had a few that just never liked it, but a couple that will just stand loose in the pasture and let me spray them....